SMARTech Community: School of Earth and Atmospheric Sciences (EAS)

The amazon hydrometeorology: climatology, variability and links to changes in weather patterns

Sun, 26 Jul 2009 22:58:59 GMT

Title: The amazon hydrometeorology: climatology, variability and links to changes in weather patterns

Authors: Fernandes, Katia de Avila

Abstract: Using ERA40 and independent observations, I assess how well Amazon surface water budget is estimated. ERA40 basin wide annual precipitation (P) agrees with observations showing an underestimation of 10%, whereas runoff (R) is underestimated by a larger margin (~25%). Observed residual of precipitation and runoff (P-R) is better estimated by ERA40 P-R than actual ET which includes soil moisture nudging. Nudging is necessary during the dry season to produce realistic ET and compensate for low soil moisture recharge during the wet season. Insufficient recharge may be caused by: underestimation of rainfall amount and intensity; a shallow root layer in the model that does not represent the deep soil water reservoir of the Amazonian forest. The physical links between changes in wet season onset and synoptic scale systems are investigated in the second part of my work. A delayed wet season onset is consistent with a decreasing number of cold air incursion (CAI) days in southern Amazon during 1979-2001. CAI variability in southern Amazon is related to SST in the tropical Pacific and Indian Oceans. The first mode of co-variability shows that during El Nio (La Nia) a strong (weak) subtropical jet stream over South America is related to decreased (increased) CAI days during SON. The second mode shows warm western Indian Ocean also related to strong subtropical jet stream. The absence a well defined subpolar jet stream, favors the northward displacement of transient waves into central South America, but shows little response in southern Amazon. CAI days reconstructed from the first and second modes do not present any significant trend in southern Amazon. CAI days reconstructed from the third mode of co-variability reproduces SON observed trend. This mode describes negative (positive) anomalies in CAI days associated with cold (warm) SST anomalies, anomalous wavetrain in the tropical Pacific and Walker Cell displacement that are unfavorable (favorable) to the incursion of CAI into southern Amazon. This mode's temporal evolution correlates with the Pacific Decadal Oscillation (PDO), suggesting that its recent gradual signal shift reflected on the interannual response of southern Pacific atmospheric patterns, hence on the behavior of transients propagation.

Laser flash photolysis studies of some gas phase reactions of atmospheric interest

Wed, 19 Aug 2009 22:58:59 GMT

Title: Laser flash photolysis studies of some gas phase reactions of atmospheric interest

Authors: Zhao, Zhijun

Abstract: Radical reactions play central roles in regulating regional air quality and global climate. Some potentially important gas phase radical reactions are being investigated in this research project, including Cl reactions with acetone, butanone, 3-pentanone, pyridine, and dimethyl selenide (DMSe), HO2 complex formation and dissociation with formic and acetic acids, and reactive and non-reactive quenching of O(1D) by the potent greenhouse gases SO2F2, NF3, and SF5CF3. The involved radicals are generated by laser flash photolysis (LFP). Temporal profiles of either the radical reactant or a product are monitored in "real time" using atomic resonance fluorescence spectroscopy (RF), time-resolved UV-visible absorption spectroscopy (TRUVVAS), or tunable diode laser absorption spectroscopy (TDLAS), allowing kinetic and mechanistic information of these reactions to be obtained. These studies provide new knowledge of the investigated radical reactions and facilitate a better understanding of their significance in atmospheric chemistry.

Spatial and temporal distribution of latent heating in the south asian monsoon region

Wed, 11 Nov 2009 22:58:59 GMT

Title: Spatial and temporal distribution of latent heating in the south asian monsoon region

Authors: Zuluaga-Arias, Manuel D.

Abstract: Information from the TRMM-CSH and TRMM-2A12 datasets is used to examine the four-dimensional latent heating (LH) structures over the Asian monsoon region between 1998 and 2006. High sea surface temperatures, ocean-land contrasts and complex terrain produce large precipitation and atmospheric heating rates whose spatial and temporal characteristics are relatively undocumented. Analyses identify interannual and intraseasonal LH variations, with a large fraction of the interannual variability induced by internal intraseasonal variability. Also, the analyses identify a spatial dipole of LH anomalies between the equatorial Indian Ocean and the Bay of Bengal regions occurring during the summer active and suppressed phases of the monsoon intraseasonal oscillation. Comparisons made between the TRMM-CSH and TRMM-2A12 datasets indicate significant differences in the shape of the vertical profile of LH. Comparison of TRMM-LH retrievals with sounding budget observations made during the South China Sea Monsoon experiment shows a high correspondence in the timing of positive LH episodes during rainy periods. Negative values of LH, associated with radiative cooling and with higher troposphere cooling from non-precipitating clouds, are not captured by any of the TRMM datasets. In summary, LH algorithms based on satellite information are capable of representing the spatial and temporal characteristics of the vertically integrated heating in the Asian monsoon region. The TRMM-CSH presents better performance than TRMM-2A12. However, the vertical distribution of atmospheric heating is not captured accurately throughout all different convective phases. It is suggested that satellite derived radiative heating/cooling products are needed to supplement the LH products in order to give an overall better depiction of atmospheric heating.

In comparing radiative transfer and chemical transport models on omi no2 retrievals

Mon, 16 Nov 2009 22:58:59 GMT

Title: In comparing radiative transfer and chemical transport models on omi no2 retrievals

Authors: Smeltzer, Charles David

Abstract: The objective of this thesis is to evaluate the sources of the differences between the NO2 satellite retrieval products provided by the Royal Dutch Meteorological Institute (KNMI) and the National Aeronautics and Space Administration (NASA). Ground studies have shown that although both products use the same satellite, these products yield different observations for NO2 tropospheric columns concentrations. This study does not validate either retrieval product, but rather indentifies the main sources for the discrepancy. There are several parameters which allow successful retrieval of NO2 vertical columns. For this study, only the difference between the radiative models and the a priori NO2 chemical transport models were considered relevant. All other parameters, such as cloud properties, slant columns, stratospheric serration and their assumptions, were held constant. Here, the models are referred to by their proprietor's acronym: "TOMRAD" refers to the radiative model used by NASA, "DAK" refers to the radiative model used by KNMI, "TM4" refers to the a priori chemical transport model used by KNMI, and "REAM" refers to the a priori chemical transport model maintained by the School of Earth and Atmospheric Sciences at the Georgia Institute of Technology. Mixing these parameters creates four retrievals for comparison. Many significant differences were identified after comparing these four retrievals. First, there are viewing geometry biases between the port side and the starboard side of the satellite retrieval for each swath. These viewing geometry biases lead to artificial periodicities in the retrievals of NO2 tropospheric vertical columns over a specific coordinate or site, such as a city. Furthermore, there were significant differences found after using different a priori NO2 chemical transport models. The low horizontal resolution of TM4 and the satellite retrieval/TM4 coupling effect compared to REAM leads to considerable questioning of the near real time application of the KNMI NO2 retrieval product. Though the TM4 model performs poorly, TM4 retrievals do perform nearly as well as REAM retrievals at capturing day-to-day variability and the spatial variability of the cities used as examples here. The retrievals using TOMRAD outperformed the retrievals using DAK when compared to the high resolution, hourly REAM a priori chemical transport model. In sum, these findings should lead to better optimizations of both the KNMI and NASA retrievals, and thus make their publicly available data products more reliable and accurate for general use.