Volume-Phase Transitions in Surface-Tethered Networks and Implications for Swelling Instabilities

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Please use this identifier to cite or link to this item: http://hdl.handle.net/1853/30402

Title: Volume-Phase Transitions in Surface-Tethered Networks and Implications for Swelling Instabilities
Alternative Title: Surface-Confined, Intelligent Hydrogels
Author: Toomey, Ryan
Abstract: The overall thrust of our research program is to develop responsive structures without the need for complex circuitry or bulky instrumentation. Our approach is to use polymers that undergo volume-shape changes in response to an external stimulus. The stimulus alters the balance of hydration forces within the polymer network, resulting in changes to the macroscopic properties. In this talk, I will discuss the role of intermolecular forces and how they can be harnessed to control volume-phase transitions in polymer networks. I will also discuss techniques for fabricating surface-confined networks, including soft lithography and photo-lithography strategies, as well as the effect of surface-confinement on the response characteristics of the polymers. Finally, it will be shown how instabilities can be induced in hydrogel microstructures to facilitate reconfigurable topographies with sensing and actuation integrated at the material level. Such reconfigurable surfaces can have important implications for variable adhesion, self-cleaning materials, and separations.
Description: Presented on September 16, 2009, from 4-5 pm in room G011 of the Molecular Science and Engineering Building on the Georgia Tech Campus.
Type: Lecture
Video
URI: http://hdl.handle.net/1853/30402
Date: 2009-09-16
Contributor: Georgia Institute of Technology. School of Chemical and Biomolecular Engineering
University of South Florida
Publisher: Georgia Institute of Technology
Subject: Hydrogel microstructures
Hydrogels
Self-cleaning materials
Separations
Variable adhesion

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