It's a great pleasure for me to welcome Francis Helen to Georgia Tech school physics Francis is visiting us from U.C. Berkeley where she's in the first year of physics and chair of the Department of Physics. Problems just grew up in New York City where she had several options one of them was ski racing which she undertook that the national level and another was physics and I learned yesterday that physics career was inspired by a teacher who spent more time on black holes than one if you will to me and I got myself thinking about this morning the sun through the indication of a signal about the way we teach a visit to ourselves it's great to know that the physics and the inspirational and after spectacular effects. I STRONGLY your crossways adult college College in New Hampshire and she majored in physics from there she writes a Stanford University where she undertook a Ph D. in experimental events metaphysics under the guidance of your biology is one of the great figures of the next master here real physics are still active to this day. After a Stanford or Francis list of Bell Labs. And the other was a post on there years before setting a professorship at University of California San Diego where she built a powerhouse lab a reputation book on primary but also time on super inductively she can relate to the problems of this great challenge is how to understand these emergent collective phenomena and they and in fact they have been out. For media conventional understanding of how or when the metals work. Moving on from U.C. San Diego Frances moves to a book League about Slovakia eight years or so ago and two years after that she was invited to become chair. Of the high. This is very deftly done absolutely spectacular Joe. Some of the world's really great. Stuff. As it was over so I should mention that want to address the. Among those which which is the ability to understand and measure the. Stream of the small systems micrograms uses the bus with that looks very much to me so I did a little googling around and found now that I understand that process is take the study Mannix off away something like not one but about a thousand of them and those were given and letters and imagine doing physics of this office on a scale it's really really really truly truly impressive the process is also along the way for the five or so the community. May weigh. Secure on the physics of a strong board which is a dying group of scientists who study your life. Stages of physics and all of the doctors nationwide worldwide and many other users in their physical society especially Jared committee on the status of women visit for the talks so today from just kind of agreed to give us a colloquialism title spin spin electronics my medical. Doctor thought it was. OK So arm Well thank you very much for inviting me it's a great pleasure to be here actually and so. I am to be talking about moments that are more for semiconductors and this is what I've been doing for a while so. Very much a large number of collaborators everything from I don't last as any other any undergrads. It's here in the room OK well I had a large number of other grads of the year is involved this project and graduate students and so forth and as well as colleagues so I'm going to start by defining the words the electronics this is not going to be a technology talk but the term arose out of technology so I'm going to introduce it there and then go on to tell you what I'm going to be talking about so the idea in Spital in spin electronics is that you know there's many components to a computer but sort of the two key components if you will one of them is the C.P.U. which of course consists of millions of transistors and there is just an example of a of a transistor and the basic idea is that the transistor is based on semiconductors and particular silicon primarily and the charge of the electron which means that it's all about voltages and currents and of course one of the primary themes here is of course the electron has spin but it is not relevant to any of these applications so the transistor it would matter if you had a magical spinless electron it would not make any difference to how this operates and so that's that's all about the charge of the electrons by contrast if I turn to the you know probably the other key component which is the hard drive so the hard drive and that's an example it's now a bit out of date even but that's the hard drive with it's you know there's the media down there with the zeros and ones back and forth. There is the leader in the right head and so forth. And the point is that this is based entirely on the electron spin and so in this case it's the opposite of course again the electron has a charge I'm not saying we've invented a magical new particle but the charges in completely irrelevant and in practical terms the bits that you write of the media they could be inflating they could be metallic it wouldn't make any difference it's the magnetic field that they produce that you write with a magnetic field in some form some of that's changing. And they could have these these elements wouldn't make any difference whether the electrons were mobile or immobile could have. Actually hear me or do I need to move the microphone closer but OK so the whole idea of an electronics where this was quiet and is that it seems like in some global sense a waste to be not taking advantage of the fact that electrons have both spin and charge and the question is So that's where the turn spin electronics came from let's take advantage of both properties and the question then you could ask quite reasonably is why and so there's a couple of current technologies that already do this and already components in most computers what's called Giant made a resistance that I assume you've had talks on J M R In the past the idea in giant magneto resistance is I have these Sara magnetic layers that are separated by a non magnetic spacer and the resistance of that could be as little as a trial lawyer by the way the resistance of that compound you know that that layer of structure depends on whether the layers are parallel or anti parallel and so the N.T. parallel state they have a higher resistance and then when they're you flip it around become Powell the resistance goes down and you detect that and so the field that is being produced by those zeros ones are able to flip the to flip those bits around and so that is an example thought to be really concrete and a little bit pedantic The idea is that the voltage depends on the magnetic field All right so I have a couple in between two different components here there's another example which is called nonvolatile RAM which uses magnetic tunnel junctions actually very related technology except for instead of having you still have to let's just call them iron layers but instead of being separated by a metallic space or a layer you're separated by insulating space a layer and so electrons tunnel from one level to the other but still the tunneling with distance depends on whether the layers of power and the parallel So again what you've got is a is is you're measuring the voltage but it is the magnetic field a factor so those are examples of some electronics and there already exist in existence of emus but what was really wanted was not those but was the idea was to create a future. Technology which involve things like spin transistors which were magnetically switchable transistors you could imagine Start for example nonvolatile logic not just nonvolatile memory but nonvolatile logic so the idea would be your you have the power shut down your computer freezes up you would you would not lose anything not even like your last few strokes would just be there you would boot up instantly you wouldn't have to have anything of you know booting up everything would just be there sort of nonvolatile logic perhaps higher order logic you could perhaps combine if you start getting exotic about this you could combine the C.P.U. and the hard drive together they are currently literally made in different factories often in different parts of the world why why don't we have a C.P.U. and a hard drive that are integrated together you can imagine that might be much faster possible new device functionality is integrated perhaps different perhaps more parallel maybe you can start creating all sorts of exotic things perhaps feel programmable now one catchin everything in this is about the last thing I'm going to say about all of this every one of those things can be done without needing spend transistors or without needing spin electronics you can have higher order logic right now if that's what you want it so again the point of all this is not to spin Electronics has still has some future there's some exciting things about it it's more quite a bit from the early days of just to spend transistor but you have to be careful particularly as a physicist that the technology you're aiming at is just not instantly obsolete. So I am not going to actually be talking much about spent electronics I'm going to tell you why this is connected to what I am going to be talking about sort of in the next slide one of the interesting things in all of this is that the idea of a magnetic semiconductor particularly one that might function at room temperature was an important step for a whole variety of reasons but for those of you who are know about the field impedance matching at the injection interface than polarization of carriers all of that is the subtlety if you can create a magnetic semiconductor and those turned out to be very few and far between. So why. Let's turn to the periodic table and ask if I wish to make a magnetic semiconductor How do I do it well the most natural thing in the world would be let's start with the magnetic element so that is all of the magnetic elements that are. There is the three D. elements and there are the four F. elements down here that's in the periodic table that's it it's actually interesting this far more superconductors than there are magnetic elements that So there's one list of magnetic materials. And there's my semiconductors again elemental I'm not there there's obviously compounds have a conductor's gallium arsenide and so forth but of my elements that's it so that's the pitch in a naive lady and this is very naive naively there's my palette to work from I can start taking it one from the green column one from the purple column and mix them together and see what I get and that might be the way you'd imagine creating a magnetic semiconductor. It turns out to be much easier said than done there are all sorts of issues that come up there are major solubility problems so the elements that I picked have metallic bonding This is a real chemistry problem there they're mostly metallic bonding they don't like to be in a covalent environment so the silicon germanium carbon has a particular covalent bonds and those metallic elements don't fit well so there are serious solubility problems that you just you know they exclude each other they precipitate out that from magnetic elements are not always in fact often are not in fact they're more commonly not magnetic than they are magnetic so just because I take iron and stick it in silicon iron in silicon doesn't necessarily fact it frequently doesn't have a magnetic moment so just taking one from column A and one from column B. does actually not work all that well even if there are so local magnetic moments these are often anti ferromagnetic Lee coupled to each other and if I want to magnetic semiconductor I actually really do want. A fair a magnetic semiconductor not an anti fair a magnetic semiconductor and so they're not only that they're often frustrated that leads to spin losses all sorts of things that are not very practical if I'm going to create something and so those of you who've heard talks in Gallia manganese arsenic which is the most popular current magnetic semiconductor with the highest transition temperature One problem is if I'm going to create something that's fair a magnetic with a high Curie temperature that's a T.C. not superconducting but three of which are usually out of direct overlap way functions which by the time you do have direct overlap of way functions you've usually got a very high electron concentration and you are therefore usually no longer semiconducting and oddly enough we have lots of ferromagnetic metals out there starting with iron so we already know how to make ferromagnetic metals by just sticking a whole ton of manganese in the gallium arsenide if you have you know if you start trying to push the Curie temperature up by just adding more and more Maggies you finally end up with a magnetic metal which is really not what we wanted in the first place something that often gets glossed over and talking about the only manganese arsenic is exactly how metallic it's become so that's a problem now all reproach to this to this was to be some of these particular solid realty We started by working with amorphous So what can and doping with worth out of the sometimes for transition metal atoms and you believe the solubility problem it turns out there's a very nice met a stable material amorphous gadolinium silicon is the one I'm mostly going to talk about gadolinium in amorphous So what can actually you can do even not very much annealing but it's a nice most stable state it's homogeneous you don't have the solubility issues so we kind of beat that problem we also be the magnetic elements the rare earth have these big four F. shells so gadolinium is magnetic in everything you put it in it just has a half filled shell that's very protected from its environment so we've eaten Problem number two we have not beaten problem number three at all in fact I'm going to show you not only is this is this a spent glass it turns out he. Well actually I'm not going to show you that today because there isn't time to show you that today but it actually turns out to be a not only a spin glass but a fabulous Lee perfect spent in the house with a perfectly frustrated interactions which is actually to do with the amorphous structure and I'm happy to talk about that one with somebody that will be time to go into that today but we definitely did not beat this problem at all we did however create something that has really extraordinary properties and so I'm now turning to the point of this talk which is really not about trying to create a new technology but is to talk about one of the call the science Tronics And my point is going to be that in a class of materials most of which you have already heard of the magnetic moments in a whole set of materials strongly affect the electrical and by the way the optical properties of the not going to show you off of it with a and you start finding magnetism very not obvious materials and it turns out that this is seen in low but not the electron concentration materials and I'll show you an example of what I mean and then the point of this talk is going to be why is that and so the real the science that I'm taking out of Tronics is this interplay between charge and spin in solid materials again electrons of course have both charge and span but when you put them in solid What's the things happen they often there are examples where the two properties become separated so that you can move charge around separately from still am which seems in a remarkable statement since ultimately you're moving I mean electron is an object but it's a complex object in the solid material so the properties of spin and charge can become separated they can become invisible so that in and I'll show you more what I mean by that but that's really the point and the question this willy a lot of this talk with me about this issue of what is so magical about low but not like from concentration materials so let me just show you two examples to make this point this is an example of this is a guy. When Nicol to a compound that has a curious temperature about seventy five Kelvin this is a plot of its electrical wires the civet is a function of temperature and you can see the connectivity is dropping it's a it's about also the resisted city is dropping even at the current temperature clearly something happens so there's a rather abrupt break at least in the slope of the road and so that is a couple that's exactly what I'm talking about so there's a couple in there of the magnetism to the electrical properties that's fine that's precisely the thing I'm interested in but now notice the scale this is that you know that's what this is a very slowly Appleford scale this is not zero so the Skilly effect here is like one percent and if you can imagine if I apply the magnetic field this is the entire size of the effects of apply magnetic field on nothing it changes in resistance that are more than a very old couple of percent or something like that so that's a material that's magnetic. So now let me turn to a magnetic semiconductor So this is a magnetic semiconductor that was known as papers back from one thousand nine hundred three it's a. Get William kind of down very small print here but it's gadolinium dope three US four gentlemen sulfide with vacancies in it which act as dope and and this is the paper this is now a plot not of reasons to hundred tippity which for the context of what I'm talking about today is just one over the other it turns out that in the where I'm the materials I'm very working on it's much better to talk about conduct to Vittie and not resist tippity and I'll show you why in a moment for now just recognize that I've switched whatever so this is a this is a semiconductor and that the conduct of a T. is with sorry this is also part of VS feel to be so it is a semiconductor if I plotted vs temperature would have the other sign of D. But look at what happens here and at Womad medic feel I have something that is completely insulating. The conduct of a T. is zero. Zero feel. And then as I search running on the magnetic field the conduct of it comes up and becomes large so that is in effect an infinite magnet a resistance infinite negative make the resistance zero carb activity feel and the the you turn it into a metal. This paper was significant mostly because it was the on here is the Sigma min which for those of you in the field know this is the man on the tele conduct of ity this paper was significant because at the time it was believed that the metal to insulator transition was a first order for phase transition. And this paper was addressing the question that it clearly isn't the activity goes very smoothly through Sigma min with no particular sign of anything happening it is in fact a second order phase from well it's more complicated even than that but the time the point was it was a second order phase transition so a magnetic field is able to change the material from an insulator to a medal and I claim that the reason for that this is possible is the electron concentration the one I showed you on the slide before was a metal with about ten to the twenty third electrons for cubic centimeter this is a material of about ten of the twentieth electrons per cubic centimeter Those are both big numbers you know this isn't astronomy So what's the difference in ten of the twentieth and ten of the twenty third it just doesn't sound terribly significant but it turns out it is so ten of the twentieth in that range is sort of this magic thing where all sorts of stuff happens and those of you who've heard talk for hi to see superconductivity on the colossal negative resistance the man unites just a whole slew of exotic materials you will have seen that number number is like ten to the twentieth show up a lot and the point is going to be that things that have a lot of electrons like ten to the twenty third are very robust metals and if I start with a very robust metallic state I can't do much to it so if I start with copper and I start putting little bits of magnetic moments into them or something like that nothing really happens I mean I don't mean to say nothing people spend a lot of their life studying things like Con. Well facts and there's some interesting critical scattering there are interesting effects but they're small so the metallic state is a very robust state and insulating say we're in is actually zero is also very robust I can stick magnetic moments and again I don't mean to say nothing happens but it's small it turns out this is kind of a magical number where it's unstable and that's really a lot of the point of this talk it is unstable precisely because it is perched at the edge between being a metal and being an insulator and like anything else when you're perched at a transition you are unstable so when you think back on all the things like height you see in Magnussen you picture their faces diagrams they're just littered with different faces. Or charge ordering things spitting glasses and the firm magnets for magnets superconductors you know all sorts of things because the sea of electrons is fundamentally unstable to probations when it's perched right at this transition so let me show you a little more what I mean by that and the do that I'm going to have to I'm going to have to do my best to introduce you to all of them instead of physics in the next half an hour so. We will see you know that there's a lot to show you why this happens but let me start with real basics of course as I've said a couple times now electrons do have both spin and charge I'm not pretending that they don't. The electrical properties are about the charge of the electron the current voltage dielectric response things like that the spin does NOT couple directly to an electric field the couples you know by by a higher order terms are Hamiltonian if we look at isolated the atoms the filled core levels are all fair and so they all exist in a let's just take helium for example one up one down and I want to stay. There paired and so there's no net moment for helium album but as soon as I have until the comet shells then I get hundreds will feel if you are paired electrons so you know even those simple one up from their lithium I filled one a. And I have one extra left on that one extra like fun is now in is you know is isn't a has a local moment it has a spin one house state and so most isolated out of the fact do have magnetic moments of an introductory pharmacare its course as you learn about how to calculate the orbital angular momentum the spinning a moment of spin or a couple plus or minus us etc so isolated Adams almost the entire periodic table has a magnetic moment as an isolated out OK but what happens when I start combining them. Chemistry is all about those outermost electrons so the coral act ons are all paired already so they have no net moment those outermost electrons which are unpaired in general as soon as I start putting them into a solid material I get chemical bonding in these bombings they've caused virtually all of the outermost left of to also become paired and therefore the spin ends up cancel. So let's be concrete about that let's start with silicon isn't it we're talking a lot about silicon so this is the silicon crystal structure it's the diamond diamond crystal structure so each silicon Adam has four nearest neighbors this is a two D. representation of that structure and the idea is that in the silicon there's my core Vaillant outermost Pons silicon as an isolated Adam has two extra has two extra electrons and they end up being in the format that you can put them in a mass spectrometer and move them around in a field and so forth but in the context of a solid material you form these bonding States and there is no net moment OK So silicon as most of you know is not a magnetic material as a solid we can talk separately about surfaces and things like that because there are interesting things about surfaces and about tiny particles of silicon but for sticking to solid fully extended solid structures it's not make that so in the context of condensed matter physics instead of chemistry we speak not about the bonding States per se we usually represent this in terms of a dancer. The electrons say and so I plot here the density of electrons States versus energy and what happens in something like silicon as I have a filled conduction band so as to call the electrons into these into these bands saved and that with a completely filled conduction band completely empty valence band and there is a gap of about one watt for unfold in silicon five and half of carbon the end result is because these states are all fill if I apply an electric field there's no place for the elect there's no available States for the electrons so this is an insulator and in the formal physics sense there is no distinction between a semiconductor and an insulator semiconductors are insulators and I'm going to mean that very precisely I can ask about the electrical conductivity and electrical conductivity of this rather simple structure and here like your conduct of it it would be X. that would be activated exponential with the band gap over T.T. So an important point here is as he goes to zero first goes to zero and it's T. increases this goes up so the conduct of ity of a semiconductor or any insulator for that matter is zero it T. O. and increases with increasing temperature and a simple model like this is because you're promoting the electrons across the band and leaving behind holes and they both carry current OK and the effect of magnetic field or magnetic impurities is going to be extremely small and there's just very little will happen so that's what can are so the covalent bonds to summarize that effectively give a close Alectryon shell so there are no mobile electrons at the fairly energy which lies in this country realize model I've done here that lives right in the middle of this gap there are no mobile electrons in there for equal zero at equal zero Now let's contrast that to copper and so copper is metallic we bond and so there is the electronic structure of a copper atom and has it has an organ in our shell than ten three D. electrons and one for us electron the important one is the four S. electron because the three D. By the way is is a for. Shell So that's a magnetic so and I put that into it copper likes to form an F.C.C. Crystal and there are all of its electrons wandering around in what we call a fairly see and the fairly see again I'm not going to try to all of those metaphysics here but the end result is the Fermi see you fill States and they minimize their energy and in doing that they end up paired so one up one down and the important thing to keep in mind is this has nothing to do with magnetic interactions This is not dipoles this is not the electrons interacting via dipoles with each other anything this is purely Powell exclusion principle plus minimising the kinetic energy and so they end up in these metallic states which are completely equal. So the end result of what I've said and you can extend this across the periodic table is that in solid the electron fin is often in fact usually not visible the electrons are in paired States whether that's an atomic cunt like you know take sodium chloride an A plus or minus you actually transfer an electron over from one of the other but you end up with electrons and paired States whether they're atomic or fairly C or covalent by and large they're all in states that are minimized such that there is no electron charge. So the net electrical charge is neutralized by the ions in a solid obviously we know the average clump of material is not does not have a net charge the electrons can be mobile which is a metal or they can be not mobile which is an insulator but either way there is no net fan so I've now hopefully convinced you that this should be no such thing as magnetism. So where does magnetism come from how do we have honored COBOL's a nickel and even get Linnean by the way being magnetic room temperature actually comes from the unfilled three billion for I felt when I said that chemistry was all about the outermost electrons chemistry is really all about the S.P. electrons the D's and F.'s don't go far enough away from the central ion to really. Sharing the chemical bonding that's you know obviously an oversimplification but loosely speaking with these enough still or it is the most complicated F. of the easy one F. are really still stuck in the original atomic orbitals and hence have a moment if there you know if there was a moment is that out and there's a moment in a solid the D.S.R. in the sort of really hard to deal with in between state where there's somewhere in between their original atomic orbitals and a completely fair we see like thing and so they're actually the most complicated to work with so those that those little bands of green in that I showed you on the periodic table those are all about until three D. and for shells you can also couch this instead of and thinking of them as atomic states you can speak of now electron bands and there's a dualism that either language works OK So the end result of that is copper or that for us electron if you ask how how many are there well that's pretty easy copper has you can just measure the density and the atomic mass of each element the end result is because there's one per copper you have ten to the twenty third electrons per cubic centimeter. And those going back to that to the bands to not really have such but and then see the light from say what happens there is because that was a half filled shell there's only one electron per album and also they can have all two you end up with an exactly half conduction band so by the time you're done taking account of all of these and putting the electrons into their Paoli exclusion driven independents say you think that we filled up. Half the conduction band and that for that to be seven electron volts just taking account of the Powell Exclusion Principle putting them into a unique state by the time you're done putting particles in a box you're at seventy even for this many electrons now seventy they may or may not connect to it's a huge number I mean it's not huge compared to the you know the rest mass of the proton or even the. West mass of the electron but it is that enormous compared to say thermal energy so for example room temperature is about twenty five million electron volts so seventy v is just enormous That's just a very large energy so why do I care about that I'll start one more point on one thinks of the reasons civilly of these metals the end result is that we write the reasons civilly as a rule not a residual with the seventy plus a row of T. and so those of you taken the physics is kind of learned about that will not as did when purity of T. is due to various things like falling on the electron electron scattering the key point here is the elect I will be able to talk about the conduct of any not resist seventy and in this limit this is just one over the other the key point is that the conduct of it he is finite at equals zero you can also say the resisted he is is finite is not infinite but that is the distinction so insulators have zero conduct of the at equal zero metals have a finite value that is actually a very important distinction so if I apply if I take a long time something that has any kind activity at all and I apply a voltage electrons will move because if I take an insulator they don't move so this is actually a precise definition of enslaver and a model is only actually formally valid at zero even my even my summary conducting state my insulating state had a finite product of a day when it was not equal zero so the definition of metals and insulators is really only precise. Well you might think well that's kind of a problem because we can't get to Tikal zero So what do we do what we do is we look at the functional form in the limit as he goes towards zero and that is where plotting conduct which we'll see some examples of is much easier to tell with the same ssion many people think about Di Rodio the derivative of the resistivity with temperature of course copper has a well copper goes down with these. Temperature wise semiconductors go up with the creasing temperature that is actually not the correct definition of metals and insulators there are metals that go the wrong way the non copper way have the opposite sign of D.O.D. T. so that will precise definition is is only one that you really only make it temperature And I forgot one point I meant to make again very small dependence of context to video on magnetic field or magnetic impurities you have to put a lot of stuff in the copper before it doesn't act like a model like really a lot you pretty much have to make it into something else like a car outside OK so what's so magical about these so I've talked about the strains inflating no carriers metal carriers so let's just very crudely let's look at the kinetic energy of the electrons in copper so the Fermi energy which was that half filled balance of the energy of the talk most most energetic electrons I write is one half you'll notice I put star but let's just for those of you know what that means you couldn't be happy otherwise just think of those one half empty squared so one of them before it is the kinetic energy like it always is if you now put in the dependence on having to satisfy the power exclusion principle it turns out that that goes like in the number of electrons the electron concentration to the two thirds power OK you've got to work through some mouth to get fresh enough very much mouth but a good senior level finance metaclass you will very quickly derive that end of the two thirds power so that for that we've got seven electron volts for copper as this said before. Now let's ask about the interaction energy and I'm this is a simple model this is just the interaction between the electrons the Coolum interaction nothing complicated Coolum interaction it's just easy for it over our and I thought dielectric constant in there to make it a little more rigorous but if you can actually if you think about it that's also the interaction between the electron and the iron core so that's above the generic expression for interaction energy interaction energy in general in a solid material. You've heard of R. and R. is the distance between them so if I talk about could be the distance between the electrons are between the electron and the iron core if I have one electron proud of that happens that those are Did those are the same as each other if I have something else then of course they'd be different but very roughly the distance between that's just stick to electrons those end of the one third power. OK And so if you look at copper that ends up being about five electron volts you have real careful what you mean by dielectric constant here but thought so that's about five electron volts Sol just naively I mean a kinetic energy dominated limit Well let's sort a good Because these are models so you'd like to think they are in a kinetic and kinetic energy is the ability to move around so copper isn't a kinetic energy dominated limit but look at the dependence end of the two thirds vs end of the one third So what happens is I start having fewer electrons in their Your first reaction for most people at least if I had fewer or fewer electrons do you think all the interaction energy goes down obviously there are further apart the Coolum energy is less that would be true if you were electrons means less Coolum interaction energy but because the kinetic energy goes like end of the two thirds power in terms of kinetic energy drops faster. So you reach the what is not completely intuitive limit that's just a few of the numbers I've mentioned we reached the not completely intuitive answer. If that there is a competition between these two energies. But it turns out well and few electrons is dominated by interactions and many electrons is dominated by kinetic energy. OK And it's all because of the palace Lucian principle so the end result is you have insulators at what Alectryon concentration including an equal zero with a sort of a trivial lemma and you have models of higher electron concentration. OK so. That's something that it's sort of a remarkable statement it's seen in you know to the surface to the electron gas things as well as three D. and the end result is that you have a quantum material there a quantum phase transition at a critical moment of electrons which I'll call in C.. And the end of the value of N C depends on things lots of things including the dielectric constant which I sort of glossed over but the there is a there is a value of N. C. that lies somewhere between about ten to the eighteen and ten to the twentieth of the twenty first and that's just built into this these trade off here and see not surprisingly like any unstable point probations create wars effects and so at this transition from insulating to metal you find that adding a magnetic field adding disorder or adding magnetic impurities almost anything you do will will change the state and that's inherently why all of the materials we find so interesting these days are all have about that electron concentration and where being dominated completely by kinetic energy leaves you with a really good model which is great for wiring up for lighting in your house making a really good insulator is really good for window glass but it's not going to lead you to all this wealth of intrinsic transitions so all the other thing that's kind of critical here is like almost everything you learn about. I'm not I'm not really going to try and teach you about Fairy Liquid theory today briefly I will mention that but it's. In the two extremes in the level like trying concentration limit you can start from an insulating state and start adding probations in your lowance of like hot for example so you can take an insulator and introduce a little bit of hopping probability from Alan the album starting from the atomic states you can start from the opposite extreme you can start from the metallic state with its you know with its particle in a box of wave functions and introduce probations in which is actually that little M four right there you can sort of think of as a probation or. Roach. At the point where you're you're exactly in between you can think of this rather globally. There is no small private or you're not a metal with a little bit of insulating properties or an insulator with a little bit of extended hopping you've got the two are equal in energy by definition at the metal to insulator transition the kinetic energy and the potential energy are sort of they're competing with each other so not one thing that happens here is that it turns out that those single particle approaches that underlie first free electron theory and secondly fairly liquid theory you they don't work so they fall apart and weighted this transition is where you start have you add one more electron to the system and instead of just adding one more electron to a state that already exists which is the orbital theory of the matter physics you end up you have one more electron and everything has to rearrange you have to recalculate the entire problem which by the way should make sense to you how is it that I get to treat you know the electrons in a solid as though I had one like you know as I had not interacting single electrons OK so I thought M. Star little star on top of the arrow but how is that that that is even faintly plausible in the answer is remarkable and is the underlying basis of what's called Fairy Liquid theory you can't do that here there is no small parameter and so you end up with you know that you really have to calculate a. Many body physics and this is goes under the general term of highly correlated electron materials so you've undoubtedly or probably if you've been coming cloakroom heard this term before these highly correlated electron materials what that's a way of saying is that the independent electron approximation even with an effect of mass doesn't work turns out and this in these highly forward the electron materials it turns out the electron spin often becomes visible meaning I now see it they're not just equal in office. It often becomes important effect deliberately adding spins is very large and you get all these instabilities you get phase transitions and things and that's all connected to this the fact that this transition so this shows up in these materials I've already mentioned the croissant I did a resistance prostates light such as one of them calcium a nice oxide the high T.C. oxides and the part where I'm going to be focusing the days on don't semiconductors which includes phosphorus silicon sort of the traditional dot semiconductor. So there so when I add one electron per extra phosphorus atom and it also turns out to a two story it also turns out to be the physics of these Where are thought to morph the semiconductors as well. OK so now I want to talk to switch gears just a little bit and talk about amorphous. And this amorphous which includes the seven conductors if you start from the crystal in structure. If you pick up any condensed matter physics book it's usually chapter one chapter one starts off by talking about the crystal a graphic symmetries so you can particularly have to tell but virtually everything is not a book starts off by talk about symmetries and things like that and so in a crystal in structure we have very well developed theories for metal for semiconductors for insulators we have found structure we have dispersion relations with what we have description we have family gas or Fairy Liquid theory etc. What happens when it becomes the more so this is just sort of a schematic of a Morpheus meeting Dawn Crystal it's not even supposed to now McChrystal and there was a lot of debate in the early days of Morpheus materials whether they really were just tiny little crystals and they are both thermodynamically and structurally distinct you can this you can actually there is a very formal way of distinguishing between an amorphous system and just tiny little crystals neither have long range order but they're nonetheless not the same structure so in that system the interesting part of course now is that I don't have. Symmetries So let's start with the basics K. is no longer a good quantum number there is no block way of this question but this is the part that I find so remarkable about introductory condensed matter physics have you with a few key exceptions but most of the properties that are being described by the introductory condensed matter physics textbooks like the novels and influence and semiconductors and superconductors and from Agnes almost all the properties that we're attempting to describe are found in amorphous systems as well. So we don't have great theories to describe amorphous metals or more first semiconductors we sort of fall back on chemistry models somewhat. But in fact virtually all the phenomena are found there so I guess I would make a rather global point at this at this moment which is to say we have to be careful that our models. Are not more specific than the phenomena they're describing and the best example I will give of that is superconductivity if you take a crystal and molybdenum the T.C. because the superconducting transition temperature is about one Calvin if you take a more first molybdenum it's seven Calvin. So personally I find it more remarkable that electrons can travel through in awfully a periodic random collected literally random because there's no short range repulsion but this collection of very disordered structure the lections can travel through that without scattering seems more amazing that they can travel through that without scattering so and in fact that led to Anderson's we casting of D.C.'s theory which was originally cast as plus and minus K. States paring into time reversed States pairing so that the realization that amorphous systems could also super If I can only could but did with higher transition temperatures even in some cases led to a generalization of D.C.'s theory that's much more profound. And so again it's we don't always have the models but. We have to recognize when our models are limiting our thinking I guess is the point and so the interesting thing is we don't have a but we do still have energy so all of the scattering in the world does not lose energy as a good quantum number as long as it's a lasting scattering and so atomic energy levels are a lot so we still have energy bans the reason I thought of density of states and not not just virtualization chips is because energy is a perfectly good quantum number still of the electron this is safe we still have a thermal energy the fairly energy can even be quite large so and so most importantly both crystalline silicon and amorphous thought and exhibit a transition from insulator to metal with increasing electron concentration and in both cases increasing what fun concentration is introduced by doping so I introduce phosphorus or introduce them or introduce whatever element I'm introducing something that is you know the give me after electrons and I increase from any calls zero which is inflating up to up to high and work becomes a mill and the probably remarkable thing is that much of the properties are actually the same between Crystal and phosphorus don't so what can and amorphous literally silicon both economic that So how does this translate into these bands Well first thing is there's the crystal in bands very grossly simplified but the crystal inbounds of silicon let's say and when I make it a more first I make There's the crystal in periodic lattice the periodic potential of a crystal lattice of the whole the ionic potential oscillates and there it is in a disordered structure so the depths of the potentials are different typically actually the distances are different this is often modeled by keeping the distances regular and just letting the depth of the potentials vary but that's the electron potential seen by the electron and what that does the first thing that that does is it broadens out what used to have sharp edges because. Well and it so there was the crystal instruction and there red thing is sort of mushed out if you will this is very very schematic and not really even to scale but it was just to get the point across so you got this distribution of distances gives what are called Band tails so you have these states that all the way through the gap what's interesting what does that tell me the let's start with I said I'm still going to introduce things that don't fit so I will introduce more phosphorus or something like that and if I end up with enough electrons that the Fermi energy is down here in the middle of this big broad band then. I get an amorphous metal and worth of metals are perfectly happy metals in fact people have learned to make a more fist metals and you know giant things that you can make I've seen a golf club made out of an amorphous novel so you can even call it what they've gotten good enough at making that you can call them rather slowly and still have the same office but the end result is that amorphous metal the electrons travel through their elastically scatter at pretty much every time every inner tonic spacing so the mean free path is very close to the inner tonic spacing which means in turn that photons don't make much difference so the resistance of the of an amorphous metal turns out to be independent of temperature roughly. It's like you already staggering every time you had it out and so there's not much else you can do to it so follow ons don't do much election electrons nothing does that much so basically with a thirty versus temperature is flat and for typical amorphous metals where you have about one electron per hour again two orders of magnitude that turns into about one hundred fifty to three hundred microns centimeters just this is just rough That's for about one electron proud of OK And so the differ were is not all that important. They really just still act like novels semiconductor so that's fine that was with the fairy energy down here you can see it kind of you know I maybe drop the number of states a little bit not a big deal but what happens up here when they found the energy lies in the middle of the gas. Well that seems to be a problem because we're before it there I told you that it was an insulator because there were no states there so when I applied an electric field the electrons were down here they had no place they could go there were no available States what if the now of the family energy lights here I have states I mean I have a lot of states and this is you know this is this is down to a very small number compared to appear I don't have a lot of states that have song so it seems a priori that I should have lost the ability that an amorphous state would not support an insulator that it would be always maybe not a very good model but at least weekly metallic at least a kind of poor model we know that's not true you know that's not true you may not know that you don't know that you know that's not true the fact that window glass is transparent is the best example of that window glass is amorphous F.I.O.S. two it has these band tails then you know again this is not to scale so they're really tiny you can see through window glass you can even see through very thick window glass the fact that you can see through it means that electromagnetic waves propagate perfectly happily through window glass that means that there are not there may be states there but it is an insulator so how can that possibly be the answer to that is there are some localization and so the key to Anderson localization is that that that that potential with varying the varying potential that I showed before leads to something called a mobility edge and the idea of the mobility edge is that it creates in some limits a wave function a block or something like a block wave that still has sort of the way like a piece that oscillates like the electron way function normally does but with an envelope and so this envelope is called the localization line. And that localization length depends on all sorts of things but the end result is if it's not the size of the sample then the electrons don't travel across the whole sample as a model and the end result of all that is I create what are called mobility edges which I was just shown here. So the idea is that electrons that have energy above the mobility edge up in the region of extended States or holes that lie below down here are mobile so I get extended states up here and then in here they're actually localized. So that's so I'm so that So that's the concept of mobility edge. And so the end result of that is an insulating state fully inflating Well if you stick a vent meter on your window glass it will not one temperature it carries a tiny bit again it will there this is very formally defined it equals zero window glass will not carry a current OK so how do I think about the electrical properties of that well these localized States it's very important understand the that what I call the localization length that is not one atom so this is not the same as creating a crystal of perfect as to where you might think of the electrons being localized like on a single atomic states these states are actually quite extended in fact the localization like to be very long localization like to be hundreds of angstroms So the electrons are not localized in one angstrom Carvell only bonded States at least in a band picture of this they're there localized over and over distance and then I'm not going to go through the derivation of my hopping probability Well that's not what I meant to do it all come back here. OK that's not good. Back Thank you. So. OK so the end result of this and again anybody who wants to look at not variable rate hopping you can the end result is that you get a formally activated hopping process just like I did back when I talked about insulators But you'll notice the so it looks so similar There's an there's the conduct of it is exponential it still goes to zero zero but I know a picture of this will one fourth power in there and that is. You know phenomenon happy to talk offline about any anybody but where that comes from it arises out of tradeoffs between energy and distance and things like that and so I end up with an activated behavior hundred simply goes to zero two equals zero goes up with increasing temperature but with a different power factor. OK And important to note this is still a single electron picture so I've drawn all these little vast lines to represent the energy of the electron states and I've acted as though the energy of those states did not depend on whether they were occupied or not occupied so this is this this is the basic of non-interacting electron theory or even Fairy Liquid theory I created I saw all the Hamiltonian I have a bunch of saved and then I start sticking electrons into them and the states are viewed as independent of their occupation so here like if I promote if this electron wants to hop these states will fall then if it wants to hop it let's say it hops or there's just a little bit higher in energy when it close to there that doesn't change the energy of any of the other states now if you think about how ridiculous that is that's impossible These are cool warm interactions how could you not have to recalculate the entire problem once you put an electron in a place different from where it was before but that's really the heart of Fairy Liquid theory and those if you're interested should take a condensed matter physics course and learn about where this comes from because it's a remarkable statement that this works very profound very deep that that works that you can treat create you can consider the occupation of the states separately from what states there are so that's obviously not completely accurate so interacting electrons on this is this is not to do more than mention is this is so this light is really just for the experts in the audience there is quantum backscattering there for this much study phenomena to do with forming loop where things interfere with each other there's the interaction between the electron. Gets gets put in is part of that little innocuous star on top of the AM is actually built into the thing to up there with with theory that's not the part I really want to talk about the part I really want to talk with is this next piece. There is in addition to the M. Star part of interacting electrons what's commonly called a cool one gap and so the cool want gap is an electron electron interaction of fact it is a many body a fact it introduces what I will call a cool long gap and that takes two forms one if the fermion or G why's here in the middle of what I call the insulating States then this isn't exactly solvable problem and you dig out what is actually called the cool and that cool one has this little quadratic form so the density of states has whatever density it would have originally had with an east east where if I don't have squared with each square is actually a minus the family from or here I'm going to show you that but eastward is the is the energy minus the Fermi energy square so this could one touches zero so the fairly energy now has no states so I told you a second ago that an Anderson localization even if I had States that to be localized and not more mobile when I add in the school long gap there actually are no states it's called a soft gap because while it's not a hard gap there is there is a node goes disease square there is a big gap there more importantly unlike the traditional band structure gaps I can't dope away from now so I've shown that here are the purple curve if I add a few more electrons so like I wanted to move the family energy away from that minimum you know like just move it up a little bit maybe up to here this cool on gap is fundamentally a many body gap and the Gap moves with it that is actually the signature of these cool on gas you can't dope away from them you can't add a few electrons or take a few electrons away that coolant gap is fundamentally tied to the Fermi energy and it is fundamentally tied to electrons repelling. Other They are also and this is going to be a really crucial point singly occupied this is to do with the fact that electrons do not actually like to be near each other so if I put one of my Tron here a second one even if it spin down the Coolum energy is large enough that that will happen so I don't break the spin up and down that requires of it that IT field but I do make it be single be occupied so the promise that I started with all of these wave functions all in the doubly occupied breaks down here. OK these are singularly occupied States so they could be up or down that's the general but since I apply fuel that's not the general So I've now created a magnetic moment out of say phosphorus sought him which a priori does not say that anything magnetic about it. Your tree and don't saw him all these non-magnetic things I've created a system not found magnetic but I've at least got the starting point which is I now have the have local moments they can interact with each other they create a magnetic susceptibility not actually complicated magnetic susceptibility it's not just Curie law because they do interact with each other has specific heat associated with the degeneracy you want to apply a magnetic field etc So that's the first example of what I'm talking about just the fact that I have these interactions has suddenly made and electrons then become visible what happens when the family energies up in the metallic region like up here well then I get some that is often called a precursor gaff and the precursor gap has a has a different form but it's sort of got like a it's a rude behavior so there is my email to see if there me so that's the precursor Gaffin is there are references for loosely listed up here that precursor get out there it's different so as again has the same property wherever the family energy is that's where that lies so if I start for example reducing the electron concentration so the feminity starts moving down this moves down with that and in fact what is. Experimentally observed is that the metal insulator transition happens we don't really know where the mobility edges in any of this metal inflated transition actually happens when this point as it moves down gets deeper and deeper and deeper and finally hit zero and once it hits zero there are no states of the fairly energy and once there's no states at the family energy there is no contact to Vittie So the transition from metal to insulator is actually determined by this cool long gap now underlying all that is the Andersen localization and things like that there is it's not that there isn't a mobility edge there is it's important for all this but the kind of crucial point is there is no actual theory that combines all these things together there's nothing that says put in disorder and then here's where the mobility edges and here's how the coolant gap and this is where the metal insulator transition happens so it's a rather we don't have a theory that can include all of these on equal footing so the way it's usually done is to put these cool and gaps in you know after the fact and that's actually the way I'm going to present the data to so that who want perfect Not surprisingly profoundly affects the conduct of it in its temperature dependence. So on the fermion if you lay up in the extended state region you get metallic conduction which again specifically means finite conduct to zero nothing about the road ity we don't know anything about that yet but in fact it's friends out that this kind of activity increases the temperature increases not surprisingly I have this little tiny gap as temperature increases you might think gosh what you just promoted electrons across this little tiny gap that would be an incomplete understanding of what happens because the gap itself is a many body gap so not only do I promote things across but actually make the gap go away so I'm like a semiconductor gap all I have to do is think about for motion across that this is a self consistent statement once I start moving things across I affect the states themselves the states don't sit there independently of their occupation so I start occupying other states I think this and the gap of self goes away. With temperature OK so the end result of all of this is I get the following form for the electron density of states with that square root thing and if I get that out for the electrical conductivity where I have a square root of T.. And the lotus that there is a Sigma not so I get my definition of a metal as T. goes to zero Sigma goes to Sigma not find I conduct the wrong side of the road which he compared a normal model but finite connectivity at equal zero. If the Fermi energy lies in the localized regime then I get an insulator with a thermal activated behavior and you're now going to get to see yet another form of activation This isn't freedom and actually there's a lot of this in three dimensions. Of whatever it does so sixty three so the colleague seventy again is activated so people zero zero but it now has a one half hour long. And that's the form of the Electrical of the electron density of states and I still change the thermal energy by doping so none of that has changed so just to prove you this is why I have to kind of wrap it up so we'll wrap it up I think I'm within a few grass home quickly so this is this is not just made up stuff this is a Morpheus get room so it can and we have metals here and we have insulators down here and this is my point here is to show you that color to be even from metal is a better thing to pot when you're near this metal insulator transmission it's very easy to see that these are going to hit people if I don't gravity pulls there are this one down to I think one tell me. You can see unless something rather unless there's some drastic phase transition like structurally that is going to hit with a finite intercept so those two are models and these guys are insulators. OK And a key point that the phosphorus has exactly the same sort of metal and insulators the one interesting point that I will leave you all with a mirror showing a couple more thoughtful. One interesting point is that the intrinsic Alectryon concentration in the amorphous systems is much higher by about two to three orders of magnitude so the N C in phosphorus silicon is ten to be eighteen and see in. More facility it is about ten to the twenty or so it's two orders of magnitude larger it's still have the inflated transition because of all the disorder and the localization of facts so this is the same at the metal insulator transition but because the there are so many more electrons things like the underlying fermion or G. is about tours of magnitude higher so the very practical level I can be at the low temperature limit at much higher temperatures phosphorus don't select and you have to be below about one tell them to see these low temperature facts amorphous yet for thought and I could be up at fifty sixty seventy Kelvin and still be seeing one correlation gaps because the temperature Well it's up to the Fermi energy is low OK so I read this comment was great past this once but really it's clear to everybody these are single reoccupied so they have they have a span. OK so the wearer thought. The basic statements we made a lot more valid always mostly worked with gadolinium which as I have and what we did some work with him which is a nice non-magnetic and all together when am I did a lot of work also with a couple of transition not all of which I'm happy to talk offline and not to talk about that day we didn't these are prepared by a lecturer when Kovacs operation also had a vacuum we've over the past this is been fifteen years of work we've done on will a lot of work by now lots of high resolution. If you can see the long list of things we've done so at level of theoretical analysis. Work will be a. Fairly linear augment a plane where something like this is a cooperative mind and so we've we've we have answers to a lot of questions if you want to ask me after the talk this is image of the structure which I really like. There's the gadolinium the big blue out by thought hims the interesting thing about the structure is that there are two types of thought in atoms there are ones that only have silicon is nearest neighbors which are still in a fully you know four little tetrahedral form and there are ones that are surrounding the gadolinium that are really in a cage like structure and they lead to two very different types of things one of them has a gap much like it would have. Thought them and the other has sort of a metallic like structure so because this is a calculation you can do projections on to the different albums and so it's just it's interesting to note that the more the structure is very forgiving it's like one out of the way it's back to making. Bonds again OK so. Who have their their so this is just quick T.M. images high resolution to their nice the amorphous no no crystal face segregation. We've also done X. lots of other structural stuff there is the it for me again I showed you that already and now I'm going to show you what happens when I add gadolinium which is sort of the point of all of this so why a gallon even a copper not much happens when I add gadolinium in into silicon in place of the yet for him to look almost identical the black curves are they you trim the level what are called the Star I get this sudden moment of the conduct of eighty so just focus on those two curves the fourteen percent gallon in which is purple and the it true that the fifteen percent yet trim which is outside of Earth so I think that's real I don't know if it's significant but there's your tree and silicon so you can see fifteen percent your trim comes down very small temperature dependence not much going on and definitely about all the prep will one blow this to start the contact of any plummets and that actually is a solid insulator. And in fact it's best to look at insulators. Far and then with the magnetic field that comes up that's kind of the key point here so when I apply a magnetic field. That conduct to be head on goes back up again. And this is best displayed on a log scale so the in that metal the metals are best displayed on a linear linear scale the insulator the best the final won't feel so this is the log of the conduct of a vs T. to the minus one house so that's how you display activated temperature dependent this thing this lock curve is that in Vero magnetic field there's an in not to test for to full successful a Tesla so that may not look dramatic but to pick a point like there is one Kelvin so one cold in the middle resistance is five orders of magnitude hundred fifty military what we couldn't measure at one hundred fifty and in zero field there it is high field these are beautiful to the minus one half the havior it is not hard to extrapolate that down to the cut activity is just it's so that's not hard to extrapolate down and what you'd find if you were ten of the seventeen at one hundred fifty million Helfen So these are just asked in fact these curves are exponentially diverge NG as you go to zero you have an infinite making it a resistance now you know seventeen orders of magnitude at one hundred fifty no one Calvin is a very large number we kind of ran out of adjectives colossal was already used up so we're stuck with extremely large Nobody is suggesting that this is going to be the basis of the next hard drive we're not going to be cooling our computers down to one hundred fifty military but this is this is seventeen orders of magnitude is a very large change in resistance. And kind of interesting part so I need to flip through and let me just show you I'll show you this curve and then I'll summarize. We can do a simple model of what's going on so if you go back to mag to Anderson localization imagine that what I have is in this material I have a lecture on moving around and I have gadolinium magnetic moments those gadolinium magnetic moments and zero field all misaligned. I have an S.F. exchange interaction and because the get Williams are all misaligned that gives an additional force of disorder. Which is what is shown. Here so I have extra disorder I now have magnetic disorder on top of the structural disorder So now imagine that I turn on a magnetic field and I line up together when the i've now reduced the disorder and when I reduce the disorder I move the mobility edge back down so what I'm doing is moving around the mobility edge which changes the conduct of it by orders of magnitude now you can't get there from thinking of battery This is miles outside of any means the mean free path this isn't a mean free path probably would never change mean that it's completely disordered already so this extra disorder does not come in in the form of changing the mean free path of the electrons it comes in in changing that coolant gap and in fact that's what we see. So what we can do is probe this is of an example of a set of data and I'm going to put past this pretty quickly this is four different samples near the metal insulator transition all different magnetic fields you can see they all look exactly the same and the interesting point is that the data completely overlays and I want to get to understand show that quickly and get to the real point. When I so I've shown you parts of conduct those all mapped beautifully onto that metal insulator physics you can also look at you know how did I know that about the coolant gap for example how do I know that it looks like a routine or it looks like a nice square the answer is experimental so we made we've made tunnel junctions either there are superconducting normal thing with a lot of aluminum that is not displaced that is the one I'm showing right now is a from the metallic side that is the cool long gap that I showed you the precursor cool of that with its root dependence on the. Side and there it is on the insulating side and those are not displaced curve that is the actual data as it comes out of the you know out of the measuring equipment so what you're seeing here is. The End zero changing that is the cooling gap of the family energy right there and as I change the magnetic field I don't change the family energy I change the mobility edge and what that doesn't turn is change the density is say at the fairly energy same thing here on the insulating side I can't go very far in slipping so I don't get the real you squared property you can see clearly it's not at that really anymore so I get the sort of the square like behavior a little bit on the insulating side and again what happens as they move as they change magnetic field is the density of states with off of zero so. This is a this is my last year of my last flight before some icing so hang in there So to summarize everything I've told you on the metallic side there is the form of the conduct of eighty there's the form the conduct of it in the insulating side there is the density of save and by change by adding these gadolinium what I do is I modify just those parameters and purple So it's sort of a remarkable thing that I don't change any of the forms of these That's why those curves lead parallel to each other I just change the pretty factor of the Sigma not the end not the team in the end too and you can do some interesting things looking at scaling so the beauty of this whole thing is that on a single sample we're able to move through the quantum phase transition of just using a magnetic field it is a remarkably simple set of parameters with no underlying theory beyond that what I said just the the Anderson localization you have you have a whole set of parameters that change in a way that we sort of understand but without being able to predict their values OK so. The last day I forgot I had one more data slide which I'll just mention there's a part we don't understand at all. Which is the tease start the thing of where does this word of the moment start mattering very high temperatures belief my belief without theory to back this up is that this is the onset of the cool one hour but we not be able to do tumbling at these kind of temperatures so I can't prove at the onset of the tunneling but it's hard to imagine you know what is happening at these temperatures and this I think is a topic I'll talk about offline with some but if you're curious the question of what controls to star is we've done a lot of experiments to understand it it's clearly a many body effect but again we're out of time so let me just get to the conclusions. OK so what I hope left you with is the sense that the at this novel insulator transition is very exotic many body physics and adding magnetic impurities into it changes things radically in fact we can pass right through the insulator trying the metal and slow transition this is very much like what is seen in things like galley manganese arsenic in various other night that exactly conductors but the theories in all those other systems those of you who've heard talks will have heard about things like magnetic pole on magnetic pole or answer awfully in a pleasurable here so that the the theories that have been developed for the crystal and systems have to at least be brought to mean the they are very specific and we see the same phenomena across the board in all the properties so can we generalize the level temperature properties can be dicks played with field dependent parameters of those little purple things which rely on many body physics known as correlation of facts but there is no simple scaling of these things and so you what controls two starts are and finally the other properties not surprisingly are also exotic we've seen very remarkable thermal conductivity as much as you see in all of the Megan is the so forth and we've been able to use this to study the mental inflated transition Thank you.