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    Structural manipulation of conjugated polymers

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    bakbak_selma_200605_phd.pdf (7.328Mb)
    Date
    2006-01-13
    Author
    Bakbak, Selma
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    Abstract
    The syntheses of new classes of conjugated polymers are presented. The synthesis of novel alkyne bridged trispyrazolylmethane ligands, their coordination behavior and their crystallographic properties are studied. A series of functionalized poly(paraphenyleneethynylene)s, PPEs, are produced by click chemistry with post and pre-polymerization. Unpredictable solid-state polymerizations of defect free conjugated polythiophenes are investigated. Finally, by click chemistry aromatic diazides and aromatic diynes are coupled to produce a library of 1,2,3-triazoles and new conjugated polymers, poly(arylenetriazoline)s.
    URI
    http://hdl.handle.net/1853/10440
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    • Georgia Tech Theses and Dissertations [23877]
    • School of Chemistry and Biochemistry Theses and Dissertations [1525]

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