Nanocrystalline Gold Arylthiolate Molecules

Show full item record

Please use this identifier to cite or link to this item:

Title: Nanocrystalline Gold Arylthiolate Molecules
Author: Price, Ryan Cameron
Abstract: This research focuses on generating, isolating, and characterizing nanophase gold clusters with diameters below two nanometers. In this size regime, the metal cores exhibit electronic and optical properties very different from those of colloidal and bulk gold, arising from quantum size confinement. The unoccupied molecular orbitals of the cores are known to accept electrons, analogous to a capacitor, but with discrete electrochemical potentials. This work describes the novel production of gold clusters with structurally rigid benzenethiolate bound to the surface, rather than typically used alkanethiolates. The Aux(benzenethiolate)y clusters are anionic and charged balanced by tetraoctylammonium cations. They are enriched in ~1.5 nm diameter cores, compared to a dominance of 1.7 nm cores when alkanethiols are used during synthesis. The Aux(benzenethiolate)y clusters are more likely to form bulk crystals and possess enhanced electrochemistry relative to Aux(alkylthiolate)y clusters. They are characterized by x-ray diffraction, carbon and proton NMR, FTIR, optical spectroscopy, mass spectrometry, elemental analysis, and thermogravimetric analysis. The etching of clusters in the presence of hydrogen peroxide and excess benzenethiol to yield smaller 1.1 nm clusters is reported for the first time in this work. These 1.1 nm clusters have a rich optical spectrum with clear electronic transitions at room temperature and orient spontaneously when deposited from solution. This oxidative etching process was applied to alkanethiolate clusters, converting ~2.0 nm polydisperse clusters into smaller clusters. This offers the potential to produce smaller gold clusters with more available charge states and may allow increase the types of thiols that can be bound to the surface of gold monolayer protected clusters (MPCs), known also as quantum dots. The use of the bulky thiol, tert-butylmercaptan to produce 1.5 nm core gold clusters is also reported, indicating sterically hindered alkanethiols can play a role in limiting the size of Aux(alkylthiolate)y clusters. These clusters were characterized by x-ray diffraction, proton NMR, FTIR, optical spectroscopy, and mass spectrometry. The clusters are potentially useful for thiolate exchange reactions to produce new types of Aux(thiolate)y clusters.
Type: Dissertation
Date: 2006-08-25
Publisher: Georgia Institute of Technology
Subject: Gold nanoparticles
Quantum dots
Raman spectroscopy
Monolayer protected cluster
Raman spectroscopy
Exchange reactions
Quantum dots
Department: Chemistry and Biochemistry
Advisor: Committee Chair: Whetten, Robert; Committee Member: Barefield, Kent; Committee Member: De Heer, Walter; Committee Member: Fahrni, Christoph; Committee Member: Phillip First; Committee Member: Wilkinson, Angus
Degree: Ph.D.

All materials in SMARTech are protected under U.S. Copyright Law and all rights are reserved, unless otherwise specifically indicated on or in the materials.

Files in this item

Files Size Format View
price_ryan_c_200612_phd.pdf 6.154Mb PDF View/ Open

This item appears in the following Collection(s)

Show full item record