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dc.contributor.authorDang, Zhengen_US
dc.date.accessioned2007-08-16T17:41:21Z
dc.date.available2007-08-16T17:41:21Z
dc.date.issued2007-05-18en_US
dc.identifier.urihttp://hdl.handle.net/1853/16143
dc.description.abstractOver the past 10 years, growing concerns over the modification of fibers have led researchers to focus on enriching the carboxyl group content of fibers by chemical oxidation and topochemical grafting. The current series of experiments continues this line of research by investigating the carboxyl group content of fibers during kraft pulping, alkaline peroxide bleaching, and 2,2,6,6-tetrametyl-1-piperidinyloxy radical (TEMPO)-KBr-NaClO oxidation system. The first experiment characterizes changes in the carboxyl group content of fibers for two sets of kraft pulps: 1) conventional laboratory cooked loblolly pine kraft pulps, and 2) conventional pulping (CK) versus Lo-Solids pulping (LS) pulps. The results indicate that effective alkali (EA), temperature, and H-factor are the primary factors controlling fiber charge during kraft pulping. Another set of kraft pulps distinguished by conventional pulping and Lo-Solids pulping were investigated to determine the effect of H-factor and pulping protocol on fiber charge. The second experiment examines the influence of alkaline peroxide treatment on elementally chlorine-free (ECF) bleached softwood kraft pulp. The effect of increased fiber charge on refining, cationic starch adsorption, and hornification was examined. The final experiment investigates the effect of TEMPO-mediated oxidation of an ECF bleached softwood kraft pulp on carboxyl group content, carbonyl group contents, degree of polymerization, and water retention value of fibers. The results show that TEMPO-mediated oxidation is useful in enriching the carboxyl and carbonyl groups to fibers, as well as enhancing the property of water adsorption of fibers. These findings suggest that: (1) kraft pulping process can be modified to obtain the target carboxyl group content, (2) terminal peroxide bleaching provides higher fiber charge which can save energy and chemical charge of subsequent refining and wet-end processes, respectively, as well as reduce hornification during drying, (3) TEMPO-mediated oxidation of fibers is capable of improving the properties of fibers, including fiber charge and water adsorption, and enhancing final paper strength.en_US
dc.publisherGeorgia Institute of Technologyen_US
dc.subjectWater retention valueen_US
dc.subjectTEMPO-mediated oxidationen_US
dc.subjectPeroxide bleachingen_US
dc.subjectKraft pulpingen_US
dc.subjectPaper physical strengthen_US
dc.subjectFiber chargeen_US
dc.subjectCarbonylen_US
dc.subjectCarboxylen_US
dc.titleThe Investigation of Carboxyl Groups of Pulp Fibers during Kraft Pulping, Alkaline Peroxide Bleaching, and TEMPO-mediated Oxidationen_US
dc.typeDissertationen_US
dc.description.degreePh.D.en_US
dc.contributor.departmentChemical Engineeringen_US
dc.description.advisorCommittee Chair: Ragauskas, Arthur J.; Committee Co-Chair: Hsieh, Jeffery S.; Committee Member: Deng, Yulin; Committee Member: Muzzy, John D.; Committee Member: Singh, Preet M.en_US


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