Induced Growth of Asymmetric Nanocantilever Arrays on Polar Surfaces

Abstract

We report that the Zn-terminated ZnO (0001) polar surface is chemically active and the oxygenterminated (0001) polar surface is inert in the growth of nanocantilever arrays. Longer and wider "comblike" nanocantilever arrays are grown from the (0001)-Zn surface, which is suggested to be a self-catalyzed process due to the enrichment of Zn at the growth front. The chemically inactive (0001)-O surface typically does not initiate any growth, but controlling experimental conditions could lead to the growth of shorter and narrower nanocantilevers from the intersections between (0001)-O with (0110) surfaces.