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dc.contributor.authorRomaner, Lorenzen_US
dc.contributor.authorHeimel, Georgen_US
dc.contributor.authorGerlach, Alexanderen_US
dc.contributor.authorSchreiber, Franken_US
dc.contributor.authorJohnson, Robert L.en_US
dc.contributor.authorZegenhagen, Joergen_US
dc.contributor.authorDuhm, Steffenen_US
dc.contributor.authorKoch, Norberten_US
dc.contributor.authorZojer, Egberten_US
dc.contributor.authorBrédas, Jean-Lucen_US
dc.date.accessioned2013-01-10T14:31:18Z
dc.date.available2013-01-10T14:31:18Z
dc.date.issued2007-12
dc.identifier.citationRomaner, Lorenz; Heimel, Georg; Bredas, Jean-Luc; Gerlach, Alexander; Schreiber, Frank; Johnson, Robert L.; Zegenhagen, Joerg; Duhm, Steffen; Koch, Norbert and Zojer, Egbert, "Impact of bidirectional charge transfer and molecular distortions on the electronic structure of a metal-organic interface," Physical Review Letters, 99, 25, (December 21 2007).en_US
dc.identifier.issn0031-9007 (print)
dc.identifier.issn1079-7114 (online)
dc.identifier.urihttp://hdl.handle.net/1853/45726
dc.description© 2007 American Physical Society. The electronic version of this article is the complete one and can be found online at: http://link.aps.org/doi/10.1103/PhysRevLett.99.256801en_US
dc.descriptionDOI: 10.1103/PhysRevLett.99.256801en_US
dc.description.abstractInterface energetics are of fundamental importance in organic and molecular electronics. By combining complementary experimental techniques and first-principles calculations, we resolve the complex interplay among several interfacial phenomena that collectively determine the electronic structure of the strong electron acceptor tetrafluoro-tetracyanoquinodimethane chemisorbed on copper. The combination of adsorption-induced geometric distortion of the molecules, metal-to-molecule charge transfer, and molecule-to-metal back transfer leads to a net increase of the metal work function.en_US
dc.language.isoen_USen_US
dc.publisherGeorgia Institute of Technologyen_US
dc.subjectBidirectionalen_US
dc.subjectCharge transferen_US
dc.subjectCopperen_US
dc.subjectElectronic structureen_US
dc.subjectGeometric distortionen_US
dc.subjectInterfaceen_US
dc.subjectMetalen_US
dc.subjectMolecularen_US
dc.subjectOrganicen_US
dc.subjectWork functionen_US
dc.titleImpact of bidirectional charge transfer and molecular distortions on the electronic structure of a metal-organic interfaceen_US
dc.typeArticleen_US
dc.contributor.corporatenameGeorgia Institute of Technology. Center for Organic Photonics and Electronicsen_US
dc.publisher.originalAmerican Physical Societyen_US
dc.identifier.doi10.1103/PhysRevLett.99.256801en_US


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