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dc.contributor.authorBartsch, Thomasen_US
dc.contributor.authorHernandez, Rigobertoen_US
dc.contributor.authorUzer, Turgayen_US
dc.date.accessioned2013-02-15T20:59:27Z
dc.date.available2013-02-15T20:59:27Z
dc.date.issued2005-07
dc.identifier.citationBartsch, Thomas; Hernandez, Rigoberto and Uzer, T., "Transition state in a noisy environment," Physical Review Letters, 95, 5, (July 29 2005).en_US
dc.identifier.issn0031-9007 (print)
dc.identifier.issn1079-7114 (online)
dc.identifier.urihttp://hdl.handle.net/1853/46202
dc.description© 2005 American Physical Society. The electronic version of this article is the complete one and can be found online at: http://link.aps.org/doi/10.1103/PhysRevLett.95.058301en_US
dc.descriptionDOI: 10.1103/PhysRevLett.95.058301en_US
dc.description.abstractTransition state theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of transition state theory thus becomes generally available for the description of reactions in a fluctuating environment.en_US
dc.language.isoen_USen_US
dc.publisherGeorgia Institute of Technologyen_US
dc.subjectChemical reaction dynamicsen_US
dc.subjectTransition state theoryen_US
dc.subjectReactanten_US
dc.subjectProducten_US
dc.titleTransition state in a noisy environmenten_US
dc.typeArticleen_US
dc.contributor.corporatenameGeorgia Institute of Technology. Center for Organic Photonics and Electronicsen_US
dc.publisher.originalAmerican Physical Societyen_US
dc.identifier.doi10.1103/PhysRevLett.95.058301en_US


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