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    Solvent effects on the vibronic one-photon absorption profiles of dioxaborine heterocycles

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    COPE_63.pdf (521.6Kb)
    Date
    2005-11
    Author
    Wang, Yan-Hua
    Halik, Marcus
    Wang, Chuan-Kui
    Marder, Seth R.
    Luo, Yi
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    Abstract
    The vibronic profiles of one-photon absorption spectra of dioxaborine heterocycles in gas phase and solution have been calculated at the Hartree-Fock and density-functional-theory levels. The polarizable continuum model has been applied to simulate the solvent effect, while the linear coupling model is used to compute the Franck-Condon and Herzberg-Teller contributions. It is found that a good agreement between theory and experiment can be achieved when the solvent effect and electron correlation are taken into account simultaneously. For the first excited charge-transfer state, the maximum of its Herzberg-Teller profile is blueshifted from that of the Franck-Condon profile. The shifted energy is found to be around 0.2 eV, which agrees well with the measured energy difference between two- and one-photon absorptions of the first excited state.
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    http://hdl.handle.net/1853/46714
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