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dc.contributor.authorAdachi, Chihayaen_US
dc.date.accessioned2013-08-30T20:20:44Z
dc.date.available2013-08-30T20:20:44Z
dc.date.issued2013-08-23
dc.identifier.urihttp://hdl.handle.net/1853/48749
dc.descriptionChihaya Adachi received his PhD from Kyushu University in 1991. In 2005 he was appointed Full Professor at the Center for Future Chemistry at Kyushu University. Since 2010 he is director of the Center for Organic Photonics and Electronics Research (OPERA) and he serves on the editorial board of Organic Electronics (Elsevier). His current research interests are in organic opto-electronics such as OLEDs, organic FETs, organic solar cells, organic laser diodes and fundamental photo-physical and electronic processes in organic solid-state thin films.en_US
dc.descriptionPresented on Friday, August 23, 2013 from 4:00 - 5:00 pm in the Molecular Science and Engineering Building room G011.en_US
dc.descriptionRuntime: 56:43 minutes.en_US
dc.description.abstractAlthough typical organic molecules are simply composed of carbon (C), hydrogen (H), nitrogen (N) and oxygen (O) atoms, carbon’s unique bonding manners based on sp3, sp2 and sp hybrid orbitals enable very complicated molecular architectures, leading to amazing functions in a wide variety of creatures and industrial products. In the last two decades, the allure of unlimited freedom of design with organic molecules has shifted a significant part of the research effort on electronics from inorganic into organic materials. In particular, great progress has been achieved in the development of organic light-emitting diodes (OLEDs). The successive progress of 1st generation OLEDs using fluorescent molecules and 2nd generation OLEDs using phosphorescent molecules solidified organic materials as a very attractive system for practical electronics. In this study, we designed new advanced electroluminescent (EL) molecules composed of only conventional CHN atoms without any precious metals. With proper molecular design, the energy gap between the two excited states, i.e., singlet (S1) and triplet (T1) excited states, are minimized, promoting very efficient spin up-conversion from T1 to S1 states (reverse intersystem crossing (ISC)) while maintaining a rather high radiative decay rate of >106/s, leading to a very high fluorescence efficiency. Using these unique molecules, we realized a very high external EL efficiency that is comparable with those of high-efficiency phosphorescence-based OLEDs. Thus, these molecules harvest both singlet and triplet excitons for light emission under electrical excitation through fluorescence decay channels. Most recently, we designed a various kind of organic light-emitting materials demonstrating intense delayed fluorescence. Even though molecules have a small energy gap between singlet and triplet excited states, we succeeded for maintaining rather high radiative decay rate, i.e., high emission efficiency. In particular, 4CzIPN showed nearly 100% internal electroluminescence efficiency, indicating delayed fluorescence is a promising pathway for converting electrically generated excitons into photons.en_US
dc.format.extent56:43 minutes
dc.language.isoen_USen_US
dc.publisherGeorgia Institute of Technologyen_US
dc.relation.ispartofseriesCOPE Distinguished Lecture Seriesen_US
dc.subjectOrganic light-emitting diodesen_US
dc.subjectOLEDsen_US
dc.titleMaterials Design for Highly Efficient Delayed Fluorescenceen_US
dc.typeVideoen_US
dc.typeLectureen_US
dc.contributor.corporatenameKyushu University. Center for Organic Photonics and Electronics Researchen_US
dc.contributor.corporatenameGeorgia Institute of Technology. Center for Organic Photonics and Electronicsen_US


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