Investigation of Reactions between Barium Compounds and Tungsten in a Simulated Reservoir Hollow Cathode Environment

Abstract

Reservoir-type dispenser hollow cathodes are currently being developed for use on NASAs Prometheus 1 mission. In these cathodes, the reaction between a barium source material and tungsten powder contained in a cavity surrounding a porous tungsten emitter produces barium vapor which is crucial to operation of the cathode.

The primary objective of this research was to investigate the reactions between tungsten and a commercial barium source material in a simulated reservoir hollow cath-ode environment. Mixtures of tungsten and a barium calcium aluminate material were sealed inside molybdenum capsules with porous tungsten closures and heated to 1000?1200?and 1300?or 100, 200, and 400 hours. Based on the reaction products, which were identified to be BaAl2O4 and Ba2CaWO6, a reaction was proposed for the barium calcium aluminate material with tungsten. The bottom pellets in the capsules were found to have reacted to a much further extent than the top pellets in all of the samples, possibly due to a temperature gradient or excessive moisture in the base of the capsules. Quantita-tive and semi-quantitative x-ray analysis results did not show a clear trend as to how the concentrations of BaAl2O4 and Ba2CaWO6 vary with time.

Most of the barium source materials are hygroscopic, and hydration of the materi-als would substantially reduce the performance of the cathode. Therefore, the environ-mental stability of several barium compounds, 3BaO??2O3 (B3A), 6BaO????2O3 (612), 4BaO????O3 (411), Ba2.9Ca1.1Al2O7 (B4ASSL), and Ba3Sc4O9, were investi-gated in order to evaluate their suitability for use as barium source materials. A micro-balance was used to measure weight gain of the materials as they were exposed to dew points of ??C and 11?t room temperature. The results showed that B3A hydrated more extensively than any of the other materials tested in the low- and intermediate-humidity environments, while the 612, 411, and B4ASSL materials were all reasonably stable in the low-humidity environment. The Ba3Sc4O9 was extremely stable compared to the barium aluminates in the intermediate-humidity conditions.